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Pyrolysis is not new and has been used to reduce the stockpile of scrap tires in the United States and plastic and rubber waste in Europe The plastics used in automobiles is roughly 22% polyurethane, 15% polypropylene, 13% polystyrene, 11% vinyl, 10% nylon, 5% polyester, and the remaining 24% resins All these materials can be pyrolyzed for chemical and energy recovery The materials from pyrolysis decompose into three major substances of pyro-gas, pyro-oil, and solid by-products The gas is similar to natural gas in performance and can be further processed into thermoplastics and asphalt applications such as shingles or paring Gasi cation is a thermochemical process in which the organic substances are converted into combustible gases with the aid of some agent, such as air, oxygen, carbon dioxide, steam, hydrogen, or some mixture of these gases.

Gasi cation has an advantage over pyrolysis since it promotes the char (residue) conversion to gas and therefore reducing the volume of solid residue and releasing chemical energy contained in the char Gasi cation is a heterogeneous solid-gas reaction The factors that in uence the kinetics of reaction in pyrolysis also in uence gasi cation The gasi cation of municipal solid waste (MSW) gives rise to low to medium heating value gases as compared to high heating value gases in pyrolysis However, the volume of gases evolved is much higher with gasi cation than pyrolysis The heating value can be increased if the material is gasi ed in an oxygen-enriched environment The gasi cation with air or oxygen has a signi cant effect on volume of gas produced and their associated heating value and the amount of remaining residue.

1. Open ab08-b.dwg from the CD-ROM. This is a drawing of a warehouse, as shown in Figure 8-4. 2. To read the text in the lower-right corner, choose Zoom Window from the Zoom flyout of the Standard toolbar.

Chemical equilibrium calculations were carried out for the pyrolysis of surrogate solid waste and its excursions at different temperatures [35 37]. The number of species can be selected depending on the data le. However, in the present study only 20 species were considered for the STANJAN code. The calculated results are shown in Figures 15.8 15.10, which include pyrolyzed gas composition (Fig.15.8), gas heating value (or energy recovery; Fig. 15.9), and pyrolyzed gas generation rate (or solid residue fraction; Fig. 15.10) as affected by the pyrolysis temperature. The results have been compared with cellulose pyrolysis. The effect of temperature on gas composition, gas yield, and gas heating value during pyrolysis of surrogate solid waste are similar in trend to those obtained for cellulose pyrolysis. High heating value of the pyrolyzed gases is produced at high temperatures from the surrogate solid wastes as seen from Figure. 15.9. At temperatures below 3000 K there is a large percentage of H2 , CO, and CO2 in the pyrolyzed gas. The increase of low-molecular-weight gases at temperatures greater than 3000 K causes a dramatic increase in the overall volume of the gas produced, as seen from Figure. 15.10. The results obtained have shown that

Steam reforming is also a thermochemical process in which the organic compound is converted into gas of very high chemical energy, such as hydrogen, using very high temperature air and steam Steam assists in the production of hydrogen at very high temperatures The amount and quality of high-energy gas produced depends upon the temperature of the reactants as well as the surrounding environment It is expected that this process will lead to signi cant development and use in the near future as this process offers cleaner and highly desirable energy conversion..

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6

The REVOLVE command creates either a solid or a surface, depending on the source object and the axis of rotation. If the source object and the object that makes up the axis form a closed figure, REVOLVE creates a solid; otherwise, it creates a surface. When you use REVOLVE to create a surface, the prompts are similar to those of the REVSURF command. I cover the REVOLVE command more fully in the next chapter (see the Drawing Revolved Solids section in 24).

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